The Greb Group

Research

The Greb Research Group explores the influence of strong ligand effects on the reactivity and physicochemical properties of p-block elements to expand the usual reactivity and property profiles of the Earth's most common elements. By dramatically altering the electronic structure through structural constraint or enabling element-ligand cooperativity, new reaction pathways for activating small molecules are discovered. Subtle changes in the oxidation states of p-block elements are achieved by interplay with redox-active ligands (Electromerism). Further, the group pursues a systematic study of the concept of Lewis acidity using data-driven methods. State-of-the-art computational approaches parallel all synthetic projects conducted in our group.

Read more
Recently Published
P. Janßen, H. Szabo+, E. A. M. Roesky+, M. Schmitt, F. Ebner, L. Greb:
A molecular model for the Ge(100) buckled dimer
Nat. Chem. 2026, Accepted Manuscript.
E. Nag, L. O. Busse, A. Albers, M. Schmitt, L. Greb:
T-Shaped Stibenium(III) Cation: Hydrostibination Without Sb─H Bond
Angew. Chem. Int. Ed. 2026, e7924667.
L. Stoess, V. D. Hannibal, L. Greb:
Valency-Controlled Multiphotochromism: Gated Switching and Photoswitchable Lewis Superacidity at Silicon
Angew. Chem. Int. Ed. 2026, e2997357.
Openings

Internship, Bachelor, Master, PhD, and PostDoc applicants are welcome to contact Lutz Greb.