The Greb Group

Research

The Greb Research Group explores the influence of strong ligand effects on the reactivity and physicochemical properties of p-block elements to expand the usual reactivity and property profiles of the Earth's most common elements. By dramatically altering the electronic structure through structural constraint or enabling element-ligand cooperativity, new reaction pathways for activating small molecules are discovered. Subtle changes in the oxidation states of p-block elements are achieved by interplay with redox-active ligands (Electromerism). Further, the group pursues a systematic study of the concept of Lewis acidity using data-driven methods. State-of-the-art computational approaches parallel all synthetic projects conducted in our group.

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Recently Published
A. Maiti, J. Zhang, R. Yadav, M. Heinrich, L. Bischof, A. Ellinger, M. Schmitt, R. Klingeler; F. Weigend, L. Greb:
NMR Spectroscopic Evidence for Magnetically Induced Ring Currents in All-Metal-Aromatic [Bi4]4+
J. Am. Chem. Soc. 2026, Accepted Manuscript.
L. Stoess, E. L. M. Paulin, F. Michel, L. Greb:
Photoswitchable Ambiphilicity: Light-Gated Frustrated Lewis Pair Reactivity and Z-Type Interaction
Angew. Chem. Int. Ed. 2026, e7924667.
I. Raz, M. Diab, K. Jaiswal, E. A. M. Roesky, L. Greb, R. Dobrovetsky:
Catecholato and biscarboranyl ligands as a platform for Lewis superacidic phosphonium ions
Inorg. Chem. Front. 2026, 13, 18, 7658-7665.
Openings

Internship, Bachelor, Master, PhD, and PostDoc applicants are welcome to contact Lutz Greb.